Under these conditions, it becomes the center of a luminous
phenomenon (electroluminescence). In fact, this is an
electromagnetically induced plasma. A plasma is a collection of
charged particles ; In this case, the plasma consists of a
stream of argon. This process being an emission technique, it is
very useful for quantitative analysis. This technique is not
new, but the recent advances in semiconductors as well as in
optical coating and devices, make it easier to develop an
instrument based on this technology, without the cost normally
associated with this category of analytical instruments.
Once the gas is ionized (charged), many spectral lines are
emitted.
Here, we think a few words regarding the technique used to
create the plasma are necessary. There are many ways of
producing light from an argon stream for analytical purposes.
The electroluminescence phenomenon includes luninescence from
all kinds of electrical discharges, such as sparks, arcs or
tubes of different kinds, operating on direct or alternating
current of low or high frequency. Recently, some experiments
were conducted in the microwave range by surface-wave-induced
plasma.
Excitation in these cases results mostly from electron or ion
collisions ; it is the kinetic energy of electrons or ions
accelerated in an electric field to which the atoms or molecules
of the gas are subjected that causes emissions of light.
By any of the previous methods, characteristic emission
spectra can be obtained for argon and each substance in it. They
usually vary for a given substance, depending on the mode of
excitation.
We developed our plasma generator and plasma cell as to
minimize the heat generation inside the cell and get a clear
spectral line for the substance of interest, i.e. nitrogen.
Once the intense line is identified, we must use a system to
filter it out. In our case, instead of a grating, prism or
tunable filter, we use an custom made optical filter with
special coating that lessens background noise considerably and
reduces spectral interference. This filter show an exceptional
bloking range. Its main characteristic is its great stability :
temperature and humidity and time will not affect its
performance it is coupled with a special lens that focuses the
optical beam.
The resulting light is directed to a special photodiode,
where an electrical current is generated. This current is
proportional to the nitrogen level in the gas stream. (Argon or
helium).
By regulating the power of the plasma and having close
control of plasma position, with the focusing electrodes, we can
optimize the sensitivity for a particular spetral ray.